METHOD FOR FORMING A WEAR RESISTANT DECORATIVE LAYER AND FLOOR PANEL

专利摘要:
method to form a wear-resistant decorative layer. The present invention relates to a method for forming a fingerprint on a substrate (4) comprising a polymer material by attaching particles in powder form (34) to the surface of the substrate.
公开号:BR112016008072B1
申请号:R112016008072-6
申请日:2014-10-22
公开日:2021-06-22
发明作者:Darko Pervan
申请人:Ceraloc Innovation Ab；
IPC主号:

专利说明:

Technical Field
[0001] The present invention relates, in general, to the field of decorative surfaces created digitally for building panels, such as floor and wall panels. The invention relates to a method of forming a printing layer and to a semi-finished product and panels comprising such a printing layer. Application field
[0002] The embodiments of the present invention are particularly suitable for use in floors, which are formed by floor panels comprising a core, a decorative layer and preferably a structured transparent wear-resistant layer above the decorative layer. The preferred modalities are laminate flooring and plastic-based LVT flooring. The description of techniques below, the problems of known technology and the objectives and characteristics of the invention will therefore be, as a non-restrictive example, directed above all in this field of application and, in particular, to floors with a surface layer resistant.
[0003] It should be emphasized that the embodiments of the invention can be used to produce a digital image on any surface, except for flat panels such as, for example, building panels, in general, wall panels, ceilings, components of furniture and other similar products that generally have large surfaces with advanced decorative patterns are preferred. The basic principles of the invention can be used to apply a fingerprint to dense surfaces such as plastic materials or metal sheets and impregnated polymer or paper or coated sheets. Background
[0004] The following description is used to describe the background and the products, materials and production methods that may comprise specific parts of preferred embodiments in the description of this present invention.
[0005] Most of all laminate flooring is produced according to a production method generally referred to as direct pressure laminate (DPL). Such laminate floors have a 6 to 12 mm thick cardboard core, a 0.2 mm thick upper decorative surface layer and a 0.1 to 0.2 mm thick lower balance layer of laminate, plastic, paper or similar materials.
[0006] The surface layer of a laminate floor is characterized by the fact that the decorative and wear properties are obtained, in general, with two separate paper layers, one on top of the other. The decorative layer is generally a printed paper and the wear layer is a transparent overlay paper, which comprises small particles of aluminum oxide.
[0007] The printed decorative paper and overlay are impregnated with melamine formaldehyde resins generally referred to as melamine resins. The impregnation is based on a two-step process, in which the paper in a first step passes through a bath of liquid melamine resin and in a second step it is dried to a sheet that is completely impregnated and covered with a dry melamine resin . The decorative paper, which before impregnation has a weight of 60 to 80 g/m2, generally comprises about 50% by weight of thermosetting melamine formaldehyde resins. The resin content in the overlay can be even higher. Aluminum oxide particles are applied during impregnation and incorporated into the resin layer on one side of the overlay paper which, during pressing, is in contact with the decor paper. The impregnated papers are laminated to an HDF core in large continuous or batch laminate presses where the resin cures under high heat (about 170°C) and pressure of 4000 to 6000 KPa (40 to 60 bars) and the papers are laminated to the core material. An embossed press plate or steel belt forms the surface structure.
[0008] Digital printing can be used to print an image on the decorative paper sheet or overlay. Digital printing is generally done before impregnation and the flexibility that digital technology offers cannot be fully utilized. It would be an advantage if digital printing was done after impregnation and onto an impregnated paper or if impregnation could be avoided. Printing directly onto a melamine impregnated paper is difficult as the ink drops applied onto the melamine layer run off during printing and especially when the dry melamine layer becomes liquid and floats during the pressing operation.
[0009] Laminate floors can also have a surface of coated paper, plastic sheets or sheets and such sheet materials are difficult to print digitally. A clear, wear-resistant protective layer which is typically a polyurethane lacquer is used to cover the printed decoration.
[0010] Luxurious vinyl tiles generally referred to as LVT floors are developed as a layered product made of thermoplastic PVC mixed with plasticizers. The name LVT is a bit misleading as a large part of the LVT floor has a plank size with a wood pattern.
[0011] Thermal molding based extrusion lamination is used to form the PVC layers. During lamination, the PVC material is heated to its softening temperature and exposed to the pressure between the rolls and cooled.
[0012] The base layer or core is mainly made of PVC mixed with chalk and/or limestone and filler materials and has a high quality printed PVC decorative sheet on the upper side. A clear vinyl wear layer with a thickness of 0.2 to 0.6 millimeters is generally applied over the decorative sheet. When PVC is heated, it becomes soft, like a paste and binds under heat and pressure to other PVC materials, but also to organic and inorganic fibers or mineral salts, when cooled to room temperature. The base layer, the decorative sheet and the transparent layer are melted or laminated together with heat and pressure in continuous or discontinuous pressing operations. The laminated sheets are, after pressing, annealed to remove stress and achieve greater dimensional stability. Lamination, pressing and annealing generally take place at temperatures between 120°C to 160°C. Annealing can be combined with aging at temperatures around 25°C to 30°C for a few days.
[0013] The decorative effects are achieved with a white decorative sheet that covers a dark core color and provides a base color for the rotogravure printing process, where special solvent-based inks are used, which bond to the surface of PVC. Such inks are difficult to combine with an eco-friendly, flexible and cost-effective printing process, especially when a digital printing method is used.
[0014] LVT floors offer several advantages over eg laminate floors such as deep stamping, flexibility, moisture-related dimensional stability, moisture resistance and lower sound. Digital printing of LVT floors is only at the experimental stage, as it is difficult to print on plastic sheet, but if introduced, it brings great advantages over conventional printing technology.
[0015] As a summary, it can be mentioned that only small volumes of floor panels are digitally printed, especially vinyl and laminate floors, mainly due to the high cost of ink and the high investment cost for industrial printers, but also due to to the fact that it is difficult to apply a fingerprint to the surface of specific materials used in such coating applications. Definition of Some Terms
[0016] In the following text, the visible surface of the installed floor panel is called the "front side", while the opposite side of the floor panel facing the subfloor is called the "rear side".
[0017] By "up" is meant towards the front side and by "down" the rear side. By "vertically" is meant perpendicular to the surface and by "horizontally" parallel to the surface.
[0018] By "binder" is meant a substance that connects or contributes to connect two particles or materials. A binder can be a liquid, powder-based, thermosetting or thermoplastic resin, and the like. A binder can consist of two components that react when in contact with each other, for example water and dry melamine.
[0019] By "fingerprint" is meant a digitally controlled ejection of fluid droplets that is used to position dyes in predefined patterns on a surface. Known Technique and Related Issues
[0020] The general technologies that are used by the industry to provide a digital print are described below. The methods can be used in part or in full in various combinations with preferred modalities in order to create a digital impression in accordance with this description.
[0021] High definition digital inkjet printers use a non-impact printing process. The printer has printheads that "shoot" ink drops from the printhead to the surface in a very precise way.
[0022] Industrial printers are generally based on a single-pass printing method, which uses fixed print heads, with a width that corresponds to the width of the printed material. The printed surface moves under the heads. These printers have a high capacity and are equipped with fixed print heads that are aligned one after the other in the feed direction, in general each print head prints one color. These printers can be tailored for each application.
[0023] A suitable print head needs to be used in order to obtain high quality and speed printing. The print head has several small nozzles that can fire and apply ink drops in a controlled manner in a sweeping pattern.
[0024] Thermal print head technology, generally referred to as bubble jet printing, uses print cartridges with a series of small chambers, each containing a heater. To eject a droplet from each chamber, a pulse of current passes through the heating element causing a rapid vaporization of the ink in the chamber to form a bubble, which causes a large increase in pressure, driving an ink droplet to out through the nozzle and onto the surface intended to be printed.
[0025] Thermal technology imposes the limitation that the ink must be heat resistant, in general, up to 300°C, because the burning process is based on heat. This makes it very difficult to produce pigment-based multi-color thermal heads.
[0026] Most industrial and commercial inkjet printers use piezoelectric printhead technology, which is the main technology used in the paving industry. A piezoelectric crystal material (commonly called piezo) in an ink-filled chamber behind each nozzle is used instead of a heating element. When a voltage is applied, the piezoelectric material changes shape, which generates a pressure pulse in the fluid that forces an ink droplet to be ejected from the nozzle. Piezo inkjet allows for a greater variety of inks and higher viscosity than thermal inkjet.
[0027] A lot of different types of ink can be used. The main components are dyes that provide the color, a binding agent that binds the dyes to the surface intended to be printed, and a liquid vehicle that transfers the dye and binder from the print head in small, well-defined droplets to the surface with a non-contact application method. The dye is either a dye or a pigment or a combination of both. Vehicle fluid can be water-based or solvent-based. The vehicle fluid evaporates and leaves the dye on the surface. UV-curable inks are similar to solvent-based inks, but the vehicle fluid cures when exposed to strong UV light.
[0028] Pigments are very fine powders of solid dye particles that are suspended or dispersed throughout a liquid vehicle. Pigment-based inks are generally mixed individually together using color pigments and various chemicals.
[0029] Pigmented inks are generally more stable to light, especially when exposed to UV light, and more fade resistant than dye-based inks. They are used in almost all paving applications. Water-based digital inks comprising color pigments are especially suitable for coating applications and can provide a high quality printing method on many different materials, as long as the materials have a surface structure that allows liquid to penetrate partially inside the top of the surface.
[0030] In general, pigments do not stick to a smooth surface. They are similar to sand particles and can be easily removed from most dry, soft surfaces. The water-based vehicle fluid is therefore generally mixed with small amounts of various other additives to provide the special ink and printing properties, such as binders which provide pigment adhesion to a surface, dot gain , pH level, drop formation, print head corrosion, fade resistance, etc. The inclusion of resins that serve as a binder in the paint composition limits the eventual amount of pigments, since both components increase the paint's viscosity.
[0031] Digital printing with water-based ink comprising color pigments is a very flexible eco-friendly method that can provide a high quality print on, for example, a paper substrate, but also on various powder-based materials. It cannot be fully used in many coating applications where special materials such as thermoplastic materials or melamine-impregnated paper are used as a substrate for decoration. Ink drops float and flow when they reach a compact surface that is unable to absorb liquid water-based ink drops. It would be a great advantage if digital images were formed with water-based ink on such compact and dense surfaces.
[0032] Several methods are used to improve the printing properties of a digital copy applied to smooth surfaces. Such methods comprise special inks and various types of coatings.
[0033] The document WO 2009/097986 describes a method for producing a special printing paper by coating a fiber-based paper with open fibers in order to improve the print quality and facilitate the impregnation after the printing step. This method can be used when a copy is applied, for example, to a melamine-impregnated paper where all the fibers are covered with a layer of melamine.
[0034] WO 2001053387 describes a transfer method for forming an impression on a PVC tile base. The method involves transferring ink from a printed design, originally onto a roll of paper, to the tile base in the lamination range. The paper is then removed with a rewind operation immediately after lamination. There is no description of the type of ink and paper or that the print could be a digital print and the method does not give any guidance on how a digital print can be obtained or transferred to a thermoplastic material.
[0035] U.S. 20110180202 describes that digitally formed images, such as sublimation dyes, can be heat transferred to vinyl coating materials. Heat activation occurs at temperatures between 160°C to 210°C and this is above the normal softening temperature of the PVC material used in LVT floors. Thus, an enhanced thermomechanical property or coating material that inhibits shrinkage from exposure to heat is needed. This is a major disadvantage and the printing method cannot be used on LVT floors comprising conventional PVC materials.
[0036] The so-called dry impregnation has been known and used for a long time. An impregnated core paper is applied within the framework of a non-impregnated decor paper and impregnation of the decor paper takes place during pressing, when the overlay resins and the core paper penetrate into the decor paper. Decorative paper can also be coated with a melamine resin on an underside and a digital print can be applied over the raw upper side. Such production methods are expensive and have been used mainly for the production of samples.
[0037] WO 2013/032387 describes that separate layers, such as a liquid melamine layer or a powder layer comprising wood fibers and melamine powder, can be applied over a core. An unimpregnated raw paper is then applied over the core and separate layer, prior to the digital printing step. The printed paper is impregnated during pressing from above by the overlay resins and from below by the resins in the separate powder layer. Although this is a flexible and efficient method, there is still room for improvement, especially related to properties such as internal bonding, production costs and production flexibility.
[0038] A disadvantage with known digital printing technologies is that inks float, especially water-based ink, when ink drops are applied on a substrate with a dense, closed surface, such as thermoplastic sheets used in floors LVT and resin impregnated papers used in laminate flooring.
[0039] The above description of various known aspects is such characterization of applicants, and is not an admission that the above description is prior art when different technologies are used, in part or completely, in various combinations. Objectives and Summary
[0040] An object of at least certain embodiments of the invention is to provide a method for applying a digital print with a preferential mode of ink comprising water-based pigments on dense surfaces. A specific objective is to provide a semi-finished product based on a dense substrate that can be used as a printing layer for a digital print. Another objective is to provide an LVT floor or a laminate floor, with a digitally printed decoration.
[0041] The invention is based on a first principle in which a printing layer is formed by ink that receives the particles and a pigment-based digital print that is formed on the printing layer. The pigments and printing layer are incorporated into a wear-resistant decorative surface composed of several layers and adapted in such a way that the pigments and printing layer are compatible with the production methods that are used to form the surface and to bond the layers of the finished product. The principle can be used to produce a digitally printed floor panel with a wear-resistant decorative surface comprising a thermoplastic or thermosetting material. The principle can also be used to produce a semi-finished print base comprising a thermoplastic or thermosetting surface with a print layer comprising the particles that can be used to provide a digitally printed decorative layer.
[0042] The invention is also based on a second principle in which a digital print is applied on a substrate with a powder-binder (BAP) printing method, in which color pigments or so-called dry ink particles are applied in dry form and linked in patterns by digitally applying the transparent white ink drops. The printing method, blank ink and dry ink have been specially adapted to provide a high quality print on a dense surface such as a thermoplastic sheet or a paper impregnated with a thermosetting resin, for example a paper impregnated with melamine formaldehyde.
[0043] According to a first aspect of the invention a method of forming a wear-resistant decorative layer, the method comprising:
[0044] provide a substrate comprising a thermoplastic material and a transparent layer comprising a thermoplastic material;
[0045] providing a continuous print layer comprising particles on the substrate or on the transparent layer;
[0046] print a digital image comprising color pigments on the print layer;
[0047] bonding the printing layer with the color pigments to the transparent layer and the substrate with heat and pressure, such that the digital image is located between the transparent layer and the substrate.
[0048] The transparent layer can be a thermoplastic sheet, preferably a PVC sheet. The clear layer is preferably a clear wear resistant layer.
[0049] The substrate may be a thermoplastic sheet, preferably a PVC sheet.
[0050] The substrate may be a core which preferably comprises a thermoplastic material, preferably PVC, and filler materials.
[0051] The printing layer can, before printing, be bonded to the substrate or to the transparent layer with a binder.
[0052] The printing layer can, before printing, be bonded to the substrate or to the transparent layer, preferably with heat and pressure.
[0053] The printing layer can be a layer of paper or loose particles.
[0054] The particles may comprise fibres, preferably cellulose fibres, more preferably at least partially bleached cellulose fibres.
[0055] The particles may comprise a thermoplastic powder, preferably a PVC powder.
[0056] Printing can be done with water-based ink, preferably comprising an acrylic binder.
[0057] Digital printing can be made with a liquid binder that binds a powder comprising the pigments.
[0058] The substrate may be a part of a building panel, preferably a floor panel.
[0059] The substrate may be a part of an LVT floor panel.
[0060] According to a second aspect, a floor panel is provided which comprises a core comprising a thermoplastic material, a decorative layer disposed on the core, wherein the decorative layer comprises a thermoplastic material and a transparent layer disposed on the layer decorative, wherein the transparent layer comprises a thermoplastic material. The decorative layer comprises a digital print provided by the ink comprising pigments and an acrylic binder.
[0061] The decorative layer may further comprise particles to which pigments are attached.
[0062] The particles may comprise fibers such as cellulose fibers or a thermoplastic powder such as PVC.
[0063] According to a third aspect, a floor panel is provided which comprises a core comprising a thermoplastic material. A decorative layer is disposed on the core, wherein the decorative layer comprises a thermoplastic material, and a transparent layer is disposed on the decorative layer, wherein the transparent layer comprises a thermoplastic material. The decor layer comprises a print layer arranged under the transparent layer. The printing layer comprises color particles and pigments bonded to said particles.
[0064] The particles may comprise fibers such as cellulose fibers or a thermoplastic powder such as PVC.
[0065] According to a fourth aspect, a flexible printing base sheet form is provided. The sheet-shaped printing base comprises a substrate and a printing layer, the substrate having two opposite surfaces, one of said surfaces comprising a thermoplastic material and is essentially covered with the printing layer. The printing layer comprises particles comprising fibers or a polymer material. Particles are attached to said surface.
[0066] The substrate may be a thermoplastic sheet, preferably a PVC sheet.
[0067] The fibers can be cellulose fibers.
[0068] The polymer material may comprise a thermoplastic material such as PVC.
[0069] The surface can be completely covered with the print layer.
[0070] According to a fifth aspect, a form of flexible printing base sheet is provided. The printing base in flexible sheet form comprises a substrate and a printing layer. The substrate has two opposite surfaces, wherein one of said surfaces comprises a paper impregnated with a thermosetting resin and is essentially covered with said printing layer, and wherein the printing layer comprises cellulose fibers, said cellulose fibers being connected to said surface.
[0071] The resin can be an amino resin, such as melamine formaldehyde resin.
[0072] The fibers can be cellulose fibers.
[0073] The surface can be completely covered with the print layer.
[0074] The surface may comprise a base color.
[0075] According to a sixth aspect, a method of forming a wear-resistant decorative surface layer with a digital print head is provided. The method that comprises:
[0076] providing a substrate comprising cellulose fibers, wherein the substrate is impregnated with a thermosetting resin and comprises a base color;
[0077] print a digital image on the substrate with a digital print head that applies ink drops of a water-based ink with a viscosity greater than about 10 cps on the substrate, and in which the ink drops are positioned in a sweep pattern, with a space between them;
[0078] apply the pigment-coated cellulose fibers on the water-based ink drops and the substrate;
[0079] binding a part of the pigment-coated cellulose fibers to the water-based ink droplets;
[0080] removing unbound pigment-coated fibers from the substrate;
[0081] apply a transparent layer comprising cellulose fibers on the digital image so that the digital image is located between the layer and the transparent substrate; and
[0082] bonding the substrate, the bonded part of the pigment-coated fibers and the transparent layer with heat and pressure.
[0083] The ink may comprise water-based glycol or glycerin solution combined with a binder.
[0084] The thermosetting resin of the substrate may be melamine formaldehyde resin.
[0085] The substrate may be a paper layer impregnated with at least 40% by weight of a thermosetting resin, preferably melamine formaldehyde resin.
[0086] The pigment coated cellulose fibers can have a fiber thickness of about 10 to 50 microns and a length of about 50 to 150 microns.
[0087] The pigment coated cellulose fibers may comprise a thermosetting resin or an acrylic binder.
[0088] According to a seventh aspect, a method of forming a wear-resistant decorative surface layer with a digital print head is provided. The method that comprises:
[0089] provide a thermoplastic substrate comprising a base color;
[0090] print a digital image on the substrate with a digital print head that applies ink drops of a water-based ink with a viscosity greater than about 10 cps on the substrate, and in which the ink drops are positioned in a sweep pattern, with a space between them;
[0091] apply thermoplastic particles comprising pigments on the water-based ink drops and the substrate;
[0092] attaching a part of thermoplastic particles to water-based ink drops;
[0093] remove unbound thermoplastic particles from the substrate;
[0094] apply a transparent layer comprising a thermoplastic material over the digital image so that the digital image is located between the layer and the transparent substrate; and
[0095] bonding the substrate, the bonded part of the thermoplastic material particles and the transparent layer with heat and pressure.
[0096] The water-based paint may comprise a water-based glycol or glycerin solution combined with an acrylic binder.
[0097] Pigments can be bonded to thermoplastic particles with an acrylic binder. Brief Description of Drawings
[0098] The invention will be described below together with the modalities and in more detail with reference to the attached exemplary drawings, in which:
[0099] figures 1a-d illustrate an LVT panel and methods for producing a printed surface digitally;
[00100] figures 2a-d illustrate a method of digital printing in two stages with binders and powder;
[00101] figures 3a-f illustrate the fingerprint on a print layer;
[00102] figures 4a-c illustrate a method for forming a print layer, for applying a fingerprint and for forming a decorative surface layer;
[00103] figures 5a-C illustrate layers of printing and digital printing.
[00104] figures 6a-e illustrate the digital printing on impregnated paper. Detailed Description
[00105] Figure 1a shows an LVT floor panel 1, which is intended to be installed floating with a mechanical locking system comprising a tongue 10 and a tongue groove 9 for vertical locking and a strip 7 with a locking element. locking 8 at one end which cooperates with a locking groove 14 at an opposite end and locks in the horizontal direction. The panel can also have straight edges and can be installed by gluing to the subfloor.
[00106] The core 5 may comprise one or more layers 5a, 5b, which preferably comprise a thermoplastic material. Said one or more layers 5a, 5b can be mainly made of PVC mixed with 20 to 80% chalk or limestone fillings, mainly in order to reduce material costs.
[00107] The core 5 has a substrate 4 on the upper side, which can be a printed decorative sheet 4a comprising thermoplastic material such as polyvinyl chloride (PVC). This decorative sheet 4a can be very thin. The decorative sheet 4a can have a thickness of about 0.05 to 0.10 mm. A transparent wear layer 3 comprising a thermoplastic material such as PVC is applied over the decorative sheet 4a. The transparent wear layer 3 can have a thickness of 0.2 to 0.6 mm. A balancing layer 6 can, in some embodiments, be applied to the back side of the core 5, in order to avoid bending. The core 5a, 5b, the decorative film 4, the transparent layer 3 and the balancing layer 6 are fused with heat and pressure in a continuous or batch press operation. Binders can also be used to bond the core 5 to the upper layers. Hot bonding of thermoplastic materials such as PVC can be done at temperatures between 130°C to 160°C and with a pressure of 5 to 10 bar. Higher pressure can be used. The clear layer can include a 2 polyurethane coating, which provides additional wear and stain resistance. The transparent wear layer 3 can be replaced by a polyurethane layer 2 which is applied directly onto the decorative sheet 4a. The transparent layer 3 may also comprise transparent PVC powder which is pressed and fused with a decorative layer 4.
[00108] LVT floors with a PVC core comprising the filling agents and which are intended to be installed floating with a mechanical locking system are generally 3 to 6 mm thick. The core 5 can be reinforced with glass fibers and can comprise several layers 5a, 5b with different densities and material composition. The underside of the core 5 can comprise grooves or cavities in order to reduce weight and save material.
[00109] Figure 1b shows a floor panel with a resilient decorative surface similar to the embodiment shown in Figure 1A. The wear-resistant decorative surface 4, 3 may comprise an underlayer 11 which is preferably softer than the upper layers 3, 4 and which may provide sound reduction. The core 5 is, in this embodiment, an HDF or MDF core 5 or a core 5 comprising a composite material, for example thermoplastic material, preferably polyvinyl chloride (PVC) or polypropylene (PP) mixed with wood fibers . Many other core materials can be used, preferably moisture resistant materials such as bonded cement agglomerates or other types of mineral baseboard material. The core 5 can further comprise a ceramic material and the resilient top layers can provide a smoother surface with lower sound. Such panels with a ceramic core can also be installed with float and can comprise a mechanical locking system.
[00110] The upper flap 9a of the tongue groove 9 can be partially formed in the core material 5. The upper layers 11, 4, 3 can also be used to form essentially the entire part of the upper flap 9a. Such a closure system comprises a tongue groove 9 with a lower part formed in the material of the core 5 and an upper part, the upper flap 9a, formed in a material different from the core 5. The upper flap 9a preferably comprises a material more flexible than core 5 which can be more rigid. Such a locking system can be used to decrease the thickness of floor panel 1 and core 5.
[00111] Figure 1c shows a piezo print head 20 that applies a liquid pigment-based ink 21 as small drops 22 on a substrate 4 which, in this embodiment, is a paper substrate 4b. The liquid ink substance evaporates and penetrates the surface 15 of the paper substrate 4b so that the pigments 23 are bonded to the surface 15 by the binder 30 of the ink 21 which, in a water-based ink, may be a liquid acrylic binder. .
[00112] Figure 1d shows a similar application on a dense surface such as a PVC sheet or a paper impregnated with melamine formaldehyde 4. The liquid substance of the water-based paint dispersion cannot penetrate the dense PVC or into the material. impregnated with melamine formaldehyde and the ink drops 22 float in an uncontrolled manner and form ink drop agglomerates. The result is a low quality print that cannot be used in coating applications.
[00113] Figures 2a-2c schematically show that a fingerprint can be formed in two steps with a binder and powder (BAP) printing method that was recently introduced in the floor application by Valinge Innovation AB, for example , as described in US Patent Applications Nos. 13/940,572 and 14/152,253, which are incorporated herein by reference in their entirety. A binder, or a so-called blank ink 30 which does not include any dyes, is applied digitally and is used to bind a powder or a so-called dry ink 31 which comprises pigments 23.
[00114] Figures 2a and 2b show that a binder pattern 30 or image is digitally formed by an ink head which preferably only applies a binding agent or so-called blank ink 30 onto a substrate 4. A dry base powder paint 31 which may comprise small colored particles, for example pigments 23, is randomly applied, preferably in dry form so that the powder particles are in contact with the binder pattern 30. The figure 2b shows a preferred embodiment, in which dry ink 31 is dispersed over binder pattern 30. Figure 2c shows that binder 30 connects some dry ink particles 31 that form the same pattern as binder 30 and a fingerprint D is formed on the substrate 4 when the unbound dry ink 31 is removed, for example, by vacuum. Various dyes can be applied and a high quality image of multiple colors can be formed in an economically efficient way since the costs for blank ink 30 and dry ink 31 are considerably lower than for conventional ink that comprises pigment dispersions. The BAP method can provide a digital print with the same or even better quality than conventional digital printing technology. One advantage is that the printhead does not have to deal with pigments that can clog the printhead nozzles.
[00115] Figure 2d shows a BAP printing equipment. The digital printer 40 applies a binder to 30 specific, well-defined portions of the substrate as a transparent image and dry ink in powder form 31 is dispersed in the binder pattern with a spreading device 41. The binder can be dried or cured by IR or hot air with a curing device 42 and unbound dry ink particles are removed by a dust removal device 43. The substrate 4 is, in this embodiment, bonded to an upper part of a core material 5 comprising wood fibers or thermoplastic material.
[00116] BAP printing can be combined with conventional inkjet printing. Most of the dyes in a digital print can be applied with the BAP printing method and only some specific colors can be printed with the inkjet printing method.
[00117] BAP printing can be used to apply a well-defined powder layer with a uniform thickness and a base color over the entire surface of a substrate 4. In general, all types of particles can be applied and a wide variety of binders in liquid and dry form can be applied.
[00118] Figures 3a and 3b show the basic principle for forming a wear-resistant decorative surface 4, 34, 23, 3 having a fingerprint comprising pigments 23. A fingerprint, preferably with an ink-based water and pigments 23 is applied on an upper side of a printing layer 34 as shown in figure 3a or on the underside of printing layer 34 as shown in figure 3b. Digital printing can be done with a conventional inkjet method or with the BAP method. The lower substrate 4, which preferably comprises a base color, and the upper transparent wear-resistant layer 3 are laminated together under pressure and heat, with the printing layer 34 and pigments 23 positioned and laminated between the two. layers. The lower substrate 4 is laminated to a core 5.
[00119] One advantage is that digital printing is applied over a print layer 34, which may have properties tailored to create a high-quality digital image and which may be better suited to the printing process than dense, smooth surfaces of the materials used in the substrate 4 and the transparent layer 3. The printing layer 34 can have favorable printing and bonding properties that allow strong lamination to the different layers used to form the wear-resistant decorative surface under heat and pressure.
[00120] The printing layer can comprise many different particles such as organic or inorganic fibers or mineral particles on the principles described below. The particles may comprise fibers 31, such as cellulose fibers as shown in figures 3a and 3b. The particles may comprise a thermoplastic material such as PVC, preferably a thermoplastic powder such as PVC powder.
[00121] Several principles can be used to form the print layer 34.
[00122] 1) According to a first principle, binders are used to bind the particles to the substrate or to the transparent layer 4 3. The BAP method can be used to bind and form well-defined layers.
[00123] 2) According to a second principle, the particles are bonded to a substrate 4 or a transparent layer 3 with heat and pressure. A wide range of particles will bond to a thermoplastic material such as PVC if the thermoplastic material is heated above the softening temperature and pressed against the particles. A very well defined layer of bonded particles can be formed when the thermoplastic material is cooled.
[00124] 3) According to a third principle, a print is applied and bonded to an upper part of a layer of loose particles which is used as a print layer 34. One of the layers, preferably the transparent layer 3, it is pressed against the print which is bonded to the layer in a preferential way with heat and transferred together with some particles from the print layer.
[00125] 4) According to a fourth principle, a separate layer of thin film in print form is used as a base for printing and the print layer with the print is then laminated and bonded to the layers.
[00126] Figure 3c shows a fingerprint according to the first principle of the invention, which can be used to produce the decorative surface layer of an LVT panel. Figure 3a shows a substrate 4 which can be a thermoplastic sheet, such as PVC sheet 4a. Substrate 4 can have a thickness of about 0.1 to 0.6 mm. A surface 15 of substrate 4 is coated with a binder 30. The binder 30 may, for example, be a water-based thermoplastic vinyl polymer such as PVA, PVAc, or a water-based acrylic polymer emulsion which preferably comprises gels to increase viscosity or a dispersion of vinyl acetate and ethylene. Binder 30 can be applied in liquid form in one or several steps and with partial drying between applications in order to increase viscosity. It is preferred that the binder has a higher viscosity than the ink applied by the printhead. The particles or fibers 32, preferably the bleached cellulose fibers, which after a pressing operation are substantially transparent, are dispersed over the wet binder 30 and the unbound fibers are removed in accordance with the BAP principle.
[00127] A piezo print head 20 is used to apply the ink drops 22 on the layer 34. The printing layer 34 prevents the ink drops 22 from floating, after printing and draining the pigments 23 during lamination when, by For example, heat and pressure are used to fuse the sheet to a core comprising the thermoplastic material, preferably PVC, and a protective layer transparent to the sheet 4a during the production of an LVT panel. High quality digital printing and strong bonding of the layers can be obtained even in the case where water-based ink 21 which preferably comprises an acrylic binder is used.
[00128] The print layer is preferably applied on a decorative sheet 4a comprising a base color. The printing layer and digital printing can also be applied on the underside of a transparent wear layer.
[00129] The PVC layers in an LVT panel are fused with heat and pressure. PVC material is non-liquid and cannot penetrate a fiber layer. Fibers which during pressing under high temperature, for example 130°C to 160°C are in contact with a PVC layer, will be fused to the surface of the decorative sheet 4a or to the transparent layer.
[00130] Preferably, the fiber-based printing layer is thin, for example with a thickness of 0.003 to 0.10 mm, especially when PVC films and cellulose fibers are used. Preferably, the binder binds most of the fibers together. Loose fibers can cause delamination. A thick fiber layer, in general, will not provide sufficient bond between the decorative PVC film 4a and the transparent wear layer, except when a binder 30, which is used during lamination, can penetrate the fibers. Bonding between the thermoplastic layers is preferably achieved by the binder 30 which binds the fibers 32 to one of the layers and the acrylic binder, wherein the ink 21 which is applied over the fibers during printing and which binds the fibers to the another layer during lamination. Two binders are preferably used to bond the PVC layers on each side of the fibers to a first binder 30 applied before applying the fibers and a second binder applied over the fibers by ink 21 during digital printing.
[00131] It is preferred that a fiber-based printing layer 34 has a thickness of about 0.03 to 0.10 mm, or a weight of about 10 to 30 g/m2.
[00132] In most applications, when a complete print is applied over the entire surface, sufficient amount of binders will be applied over the fibers 32 by the binder in ink 21. In some applications, additional binders may be needed in order to avoid delamination. Such binders can be applied by a separate row of printheads which apply blank ink which comprises a binder, preferably an acrylic binder, onto the fibres. Binders can also be applied to both layers.
[00133] The method can be used to apply an in-line printing layer onto a sheet which is then digitally printed in a second production step. The method can also be used to produce special coated sheets or papers that constitute a printing base 35 and that can be supplied in rolls or as sheets to a factory where the final digital printing takes place.
[00134] Figure 3D shows that similar methods can be used to form a printing layer 34, for example, on a paper 4b that is impregnated with a thermosetting resin 24, for example, a melamine formaldehyde resin. Paper 4b can be a decorative paper with a base color and the print layer 34 is applied over the colored surface. It can also be an overlay paper and the printing layer is applied over a surface which after lamination forms the underside of the overlay. Bonding can be achieved only by coating the dry melamine surface with water. The dry melamine formaldehyde layer melts and binds the particles 32, preferably the surface fibers impregnated with melamine formaldehyde. The melamine formaldehyde impregnated paper, which generally comprises a resin lining of 50% and more, is covered by an open fiber structure, preferably bleached cellulose fibers, which preferably comprise a high resin content. smaller than the paper substrate. Resins in the upper fibers to be printed are only needed to bind the paper fibers during printing and the resin content can be as low as about 10% by weight. The superior fibers can be essentially free of resins and the ink drops comprising pigments 23 can be applied directly onto the fibres. This eliminates floating and sagging during lamination. Melamine can also be applied in liquid form over the dry melamine layer. The application of binder and powder can be done as a separate production step after impregnation or continuously in conjunction with impregnation. The thickness of a fiber-based printing layer is less essential when papers impregnated with melamine 4b are used as substrate, as melamine floats during lamination and all fibers are automatically impregnated and bonded by the liquid melamine.
[00135] Many different organic and inorganic particles and binders can be used to form a printing layer 34 on a substrate and the particles and binders can comprise pigments or other types of dyes. However, it is an advantage in some applications if the particles are such that they are transparent or at least semi-transparent when heat and pressure are applied during lamination. The substrate's base color can be used as one of the colors in the print and the applied digital image will not be interrupted by the particles that make up the print layer. The particles and binder must be adapted to the materials and methods that are used to bond the decorative layer to a panel core and to protect the print from wear.
[00136] Particles that are compatible with various polymeric materials and especially thermoplastic material such as PVC, but also thermosetting resins are, for example, cellulose fibers, kaolin, conversation, chalk, limestone, carbonate, feldspar, fibers of glass, aluminum oxide, silicon carbide, silica and similar minerals.
[00137] Separated polymeric materials can be used as binders to bind particles to a thermoplastic sheet material, such as a PVC sheet. Bonding also takes place in accordance with the production of PVC sheets and preferably in liquid form can be applied to the surface of the sheet and can connect to the particles.
[00138] Fibers and other particles can also be bonded to a PVC material, for example a PVC sheet without binder. The sheet can be heated and pressed against a layer of particles and particles that are in contact with the hot sheet will be bonded. A thin and very well defined layer of particles can be applied by the hot pressing method and a strong bond can be obtained.
[00139] Figure 3e shows a substrate 4, which in this modality is a PVC sheet 4a. The thermoplastic particles 33, preferably PVC powder, for example VESTOLIT, are applied over a binder which may be a water-based thermoplastic polymer, for example PVA, PVAc or an acrylic polymer emulsion. VESTOLIT powder results in a strong bond between individual particles and PVC layers when final pressure and heat are applied and the thickness of the printing layer can be much greater than when fibers or minerals are used as a printing layer. . The porous microstructure of the plastic particles constitutes a printing layer that prevents ink droplets from floating, and the pigments 23 are attached to the particles. PVC powder can have a base color, but it can also be transparent, like VESTOLIT, when fused with heat and pressure. A second powder layer 33b comprising thermoplastic particles can be applied over the fingerprint and can form a protective wear layer that can replace the transparent sheet 3. The second layer 33b can also comprise a bonding agent and preferably , also wear resistant particles such as aluminum oxide particles. The layers can be applied and bonded to the substrate by the BAP method as a dry ink 31.
[00140] The methods described above can be combined. The particles can comprise, for example, a mixture of fibers and PVC powder, such as VESTOLIT, and such a mixture can provide increased bonding between the layers. The binding properties of one of the particles in a printing layer can be enhanced if, for example, vinyl-based polymer powder, such as VINNAPAS, is mixed with the particles.
[00141] Figure 3F shows that an LVT floor panel can have an upper core layer 5a comprising PVC, fillers and pigments 23 and that core layer 5a can replace the decorative sheet as a color barrier against the other parts of core 5b which have an undefined color that can be transported through the printed pattern. The printing layer 34 comprising the plastic particles 33 is applied directly onto a core layer 5a, and the ink drops comprising the pigments 23 are applied onto the plastic particles 33.
[00142] Figure 4a schematically shows the equipment that can be used to form the printing layer 34 or a printing base 35 in four steps in a preferred mode of production. The equipment comprises a binder application device 41, a dispersing device 42, a curing device 43 and a dust removal device 44. The binder 30 can be applied with the binder application device 41 which is, for example , a roll coating in one or several steps over the top surface 15 of the substrate 4. Initiators can also be used. The rollers can have a structured surface such that a sweep-shaped binder pattern is formed. The binder can also be applied by spraying or digitally with a piezo head. Roll coating is preferred in many applications as the binder can have a much higher viscosity than when spray nozzles or piezo fingerprint heads are used. In a second step, the powder, fibers in this preferred modality 32, are dispersed over the wet binder 30 with the dispersing device 42. The binder is, in a third step, cured with the curing device 43 which may comprise a light IR, hot air, UV light, etc. depending on the binder. Finally, in a fourth step, unbonded fibers 32 are removed with the dust removal device 44, where air and vacuum currents can be used, and a substrate 4 with a printing layer 34 is formed.
[00143] Several other methods can be used. Binder drying or curing can occur when unbound particles are removed. Dust can be applied accurately and unbound dust removal can be excluded. Dispersion can be replaced by application methods, where the substrate with the binder is pressed against powder or where the substrate passes through a container filled with the powder.
[00144] The substrate 4 with the printing layer 34 can be used as a semi-finished print base product 35 and can be transported in rolls or sheets to another location where the digital printing is done. The print layer 34 and the print base 35 can also be formed in conjunction with the digital printing operation.
[00145] Figure 4b shows the digital printing on the print layer 34 or on a print base 35 with a digital printer 40 comprising five print heads 20, each comprising a color. The printing layer 34 comprises in this embodiment fibers 32 which are joined to substrate 4 with a binder 30. Digital printing can be done with conventional printing methods, where pigments 23 are included in the liquid ink applied by print heads 20 Digital printing can also be done partially or completely with the BAP printing method as described above, wherein the liquid blank ink comprising a binder and the dry ink comprising the pigments are applied in two separate steps.
[00146] Figure 4c shows an upper part of an LVT panel 1. A thermoplastic sheet 4a such as a PVC film with a printing layer 34 and a fingerprint comprising the pigments 23 is positioned between the core 5 and the layer wear layer 3. Alternatively, the printing layer 34 and the fingerprint with the pigments 23 are positioned on the underside of the transparent layer 3 (not shown). The very thin printing layer 34 will be surrounded by the printing layer binders 30 and the ink which during pressing can penetrate the printing layer in such a way that strong lamination of the layers can take place. Pigments 23 are firmly attached to the print layer and run-off can be avoided. Wear layer 3 comprises a polyurethane layer 2 on the upper side.
[00147] According to one aspect of the invention, an LVT floor panel is provided with a core 5 comprising a thermoplastic material and fillers, an upper transparent surface layer 3 and a decorative layer 4 between the core 5 and the transparent layer 3. Decorative layer 4 comprises a digitally printed decoration, preferably provided by the ink comprising the water-based pigments and the acrylic binder.
[00148] According to another aspect of the invention, an LVT floor panel is provided with a core 5 comprising a thermoplastic material and fillers, an upper transparent surface layer 3 and a decorative layer 4 between the core 5 and the transparent layer 3. Decorative layer 4 comprises fibers 32, preferably cellulose or mineral fibers.
[00149] Figure 5a shows a method for forming the printing layer 34 and the printing base 35 according to the second principle of the invention. The particles are dispersed in one on a carrier or vehicle by a dispersing device 42. A substrate 4, which may be a thermoplastic sheet, preferably a PVC sheet, is preferably heated by a press roller to hot 45 and pressed against the particles, for example the fibers 32, preferably cellulose fibers, in such a way that a thermal bond is carried out between the particles 32 and the substrate 4.
[00150] Hot bonding can also be used to form a printing layer in applications where the particles are dispersed over a hot core layer which preferably comprises the pigments. A hot wood plastic composite board comprising PVC or PP mixed with wood fiber based fillers can also be dispersed with particles, preferably fibers after extrusion when the board is still hot.
[00151] Figure 5b shows a method for forming the printing layer according to the third principle of the invention. The particles, preferably fibers 32, 33, of thermoplastic powder such as PVC powder or minerals are dispersed, for example, as a continuous powder layer on a carrier and they are not bonded to a substrate. The continuous powder layer is used as a print layer 34 for the digital print which is applied by a digital printer 40, wherein loose particles from the continuous powder layer 34. The digital print can be printed by an ink comprising a pigment dispersion. A thermoplastic sheet which can be a substrate 4, which comprises a base color or a transparent sheet 3 is heated and pressed against pigments 23 which are transferred to the thermoplastic sheet together with the particles of the printing layer 34, for example fibers 32 or thermoplastic powder 33. It is an advantage if the pigment dispersion in the paint comprises acrylic resins which provide a strong bond between the pigments and the thermoplastic sheet. Such a method for transferring a fingerprint from powder-based particles can also be used without hot bonding. A melamine formaldehyde paper can comprise a moist melamine binder and can be pressed against printing with the powder. A thermoplastic sheet comprising a binder can also be pressed against the print.
[00152] Figure 5C shows a method for forming the printing layer 34 and the printing base 35 according to a fourth principle of the invention. The printing layer 34 is a paper layer, preferably a raw unimpregnated overlay paper which comprises fibers which are transparent or semi-transparent after lamination. A digital print is preferably applied onto one side of the printing layer 34, which is laminated to the upper transparent layer 3 and a lower substrate 4. The transparent layer 3, the printing layer 34 and the substrate 4 are laminated to a core 5. It is an advantage if the paper is thin and has a weight of about 40 to 60 g/m2. The bond strength can be increased if, for example, ink blank comprising an acrylic binder is applied digitally or with roller coating on one or both sides, preferably after the printing step. Paper can be replaced with a non-woven material made from long fibers, bonded together by chemical, mechanical, thermal or solvent treatment means.
[00153] The hot bonding and lamination of the layers according to the second, third and fourth principles is preferably carried out at temperatures of about 120°C to 160°C. The four principles described can be combined. A first layer of particles can be applied, for example, with hot bonding and a second layer of particles can be applied by using a binder.
[00154] Particles can, in any embodiment of the invention, comprise color pigments that can be used to provide a print layer with a base color.
[00155] Figure 6a shows a preferred embodiment, similar to the embodiment shown in Figure 3d, comprising a core 5, and a wear-resistant decorative surface layer 12, comprising a paper substrate 4b impregnated with a thermosetting resin 24, preferably a melamine formaldehyde resin 24, a printing layer 34 which preferably comprises the cellulose fibers and pigments 23 applied by a digital print head to the printing layer 34. The print is covered by a wear layer 3, which in this embodiment is a conventional transparent overlay impregnated with a melamine formaldehyde resin 24. Overlay 3 comprises wear resistant particles 25. The three layers are heated, pressed and laminated to the core 5. This preferred embodiment can be used to form a printing base 35. Cellulose fibers 32 are applied as a printing layer 34 and bonded to a substrate of paper 4b impregnated with a thermosetting resin 24, preferably a melamine formaldehyde resin. The cellulose fibers 32 can be bonded to the impregnated paper 4b with a thermosetting binder, preferably a melamine formaldehyde resin, which can be applied as a dry powder or as a liquid. The paper 4b and applied cellulose fibers 32 may comprise a base color. The fiber type and/or fiber size and/or fiber orientation are preferably different in the printing layer and in the paper substrate 4b. The fibers are preferably about 50 to 300 microns long and about 10 to 50 microns thick. The paper fibers can be adapted to cover a core 5 and provide strong lamination to the core, and the cellulose fibers in the printing layer 34 can be adapted to receive and bind the ink drops. Preferably, the fibers in the printing layer 34 are shorter and comprise a smaller amount of resin than the fibers in the paper substrate 4b which can be longer and which can be coated with a higher resin content. The resin content in the paper substrate is preferably at least about 40% by weight.
[00156] Figures 6b to 6d show that the BAP method can be used to apply a fingerprint directly onto a dense substrate, without a print layer. A preferred embodiment comprises a core 5, a paper substrate 4b impregnated with a thermosetting resin 24, preferably a melamine formaldehyde resin and a fingerprint applied on the substrate 4b by the BAP method. The printing method, blank ink or binder and dry ink or dyes have been specially adapted to provide a high quality print on a dense surface, preferably a paper comprising a base color and impregnated with a resin of melamine formaldehyde or a thermoplastic sheet.
[00157] A first problem that needs to be solved is the fluctuation of ink drops 22 when they collide, for example, with a dense surface impregnated with melamine formaldehyde, especially a surface comprising a high melamine formaldehyde resin content greater than 40 % by weight of the impregnated paper. This can be resolved with blank ink which has a high viscosity and with a printing method that preferentially places the ink drops side by side and apart from each other in a sweeping pattern so that the drops ink are not in contact with each other. Agglomerates of ink droplets attracted to each other by surface tension should be avoided.
[00158] A suitable blank ink that preferably can be used on a high viscosity printhead designed to run with a viscosity of about 10 to 12 cps and higher, such as a Fuji printhead, may be a solution. of glycol and glycerin-based can be combined with a binder. A blank ink suitable for a high viscosity printhead, for example, may comprise about 20% water, 60% glycerin, 10% diethylene glycol and 10% binder, preferably a binder comprising a dispersion of thermally crosslinkable acrylate copolymer.
[00159] A second problem that needs to be solved is the draining of pigments during pressing, when the melamine resin is in a liquid phase. This problem can be solved with pigments that are bonded to a pigment vehicle such as wood fibers 32 that do not float as they are pressed against the paper substrate 4b during pressing and curing.
[00160] A suitable dry ink preferably comprises cellulose fibers 32 coated with pigments bonded to the fiber surface with a thermosetting resin, preferably a melamine resin or an acrylic binder.
[00161] Such pigment binding can be achieved with production methods, where pigments and fibers in a first step are mixed with a powder. In a second step, water comprising, for example, molten melamine resins or a water-based acrylic binder is mixed with the dry powder and the wet mixture is then heated and dried. In a third step, the dry powder is ground and sieved so that a suitable particle size is obtained.
[00162] The coated and sieved fibers preferably have a length of about 50 to 150 microns and a thickness of about 10 to 50 microns. Such fibers are easy to apply with dispersion and to remove with drafts and provide high resolution printing. The fibers will also absorb a substantial part of the liquid ink and ink drop floating will be eliminated after dry ink application.
[00163] The coated pigment and fibers are preferably sieved in a fourth production step and mixed with dry melamine particles in powder form that melt and bond the coated fibers with the surface of the impregnated paper when they are in contact with the liquid ink drops on white.
[00164] Figure 6b shows the blank ink drops 22 applied on a paper substrate 4b impregnated with a thermosetting resin 24, preferably a melamine formaldehyde resin. Ink drops 22 are applied in a sweeping pattern and spaced apart from each other with an S gap, which can be about 10 microns or larger.
[00165] Figure 6c shows dry ink particles comprising pigment-coated fibers 32 applied onto blank ink drops 22 and paper substrate 4b.
[00166] Figure 6d shows the paper substrate 4b when the unbound dry ink particles have been removed, for example, by air currents, such that only the coated fibers 31 bound by the blank ink drops 22 are bound. to substrate 4b. The individual fibers 32 can be connected to several ink drops 22. The fibers will overlap the space S, and the space S between the ink drops 22 will not interrupt the digital image D.
[00167] Figure 6e shows the press and curing of the wear-resistant decorative surface layer 12. The core 5 comprises a balancing layer 6 which may be a mixture of wood fiber powder 32 and melamine powder 24c. In some applications, a similar powder layer 32 can be applied under the paper substrate 4b in order to increase impact strength and to allow for the formation of a deep stamp. Fingerprint D may be covered by a wear layer 3 which, in this embodiment, may be a conventional transparent overlay impregnated with a melamine formaldehyde resin 24. Overlay 3 comprises wear resistant particles 25. Wear layer 3 may also be be a powder overlay comprising wear resistant particles 25 and binders 24. The layers and fingerprint D are heat pressed by an upper 46a and lower 46b press table and laminated to the core 5.
[00168] The BAP print described above can also be used to form a digital print on a sheet. The substrate may comprise a thermoplastic film and the dry ink 31 may comprise thermoplastic particles and pigments. Pigments can be bonded to plastic particles with an acrylic binder. Pigments can also be incorporated into the thermoplastic particle body. The plastic particles preferably have a diameter of about 50 to 150 microns.
[00169] BAP printing can be applied onto the substrate in a separate operation or it can be applied in-line when the substrate is positioned over a core material.
[00170] The BAP method can also be used to apply a layer of paint to a surface. A blank ink raster pattern can be applied to substantially the entire surface of a sheet or paper and the particles can be bonded, such that a printing layer with a well-defined layer thickness can be formed when the particles unbound are removed.

权利要求:
Claims (14)
[0001]
1. A method for forming a wear-resistant decorative layer, characterized in that it comprises: providing a substrate (4; 4a; 5) comprising a thermoplastic material and a transparent layer (3) comprising a thermoplastic material; providing a continuous print layer (34) comprising particles in the substrate (4; 4a; 5) or in the transparent layer (3), wherein the print layer (34) comprises loose particles, and wherein the particles comprise a powder thermoplastic (33) printing a digital image comprising color pigments (23) on the print layer (34); and bonding the print layer (34) with the color pigments (23) to the transparent layer (3) and the substrate (4; 4a; 5) with heat and pressure, such that the digital image is located between the layer transparent (3) and the substrate (4; 4a; 5), wherein the transparent layer (3) is a thermoplastic sheet, and wherein the substrate is a thermoplastic sheet (4a).
[0002]
2. Method according to claim 1, characterized in that the transparent layer (3) is a PVC sheet.
[0003]
3. Method according to claim 1 or 2, characterized in that the substrate is a PVC sheet.
[0004]
4. Method according to any one of the preceding claims, characterized in that the printing layer (34) before printing is bonded to the substrate (4; 4a; 5) or to the transparent layer (3), preferably, with heat and pressure.
[0005]
5. Method according to claim 4, characterized in that the printing layer (34) is bonded to the substrate (4; 4a; 5) or to the transparent layer (3) with a binder (30).
[0006]
6. Method according to any one of the preceding claims, characterized in that the particles comprise fibers (32) preferably cellulose fibers, more preferably at least partially bleached cellulose fibers.
[0007]
7. Method according to any one of claims 1 to 6, characterized in that a thermoplastic powder (33) is a PVC powder.
[0008]
8. Method according to any one of claims 1 to 5, characterized in that said particles comprise organic fibers, inorganic fibers or mineral particles.
[0009]
9. Method according to any one of the preceding claims, characterized in that the printing is done with water-based ink (22) which preferably comprises an acrylic binder.
[0010]
10. Method according to any one of the preceding claims, characterized in that the fingerprint is made with a liquid binder (30) that binds a powder (31) comprising pigments.
[0011]
11. Method according to any one of the preceding claims, characterized in that the substrate (4; 4a; 5) is a part of a building panel, preferably a floor panel (1), or in which the substrate (4; 4a; 5) is a part of an LVT floor panel.
[0012]
12. Method according to any one of the preceding claims, characterized in that it further comprises laminating the transparent layer (3) and the substrate (4, 4a, 5) to a core (5, 5a, 5b) with heat and pressure.
[0013]
13. Method according to claim 12, characterized in that the core comprises thermoplastic material, preferably PVC.
[0014]
14. Method according to any one of the preceding claims, characterized in that said digital image is applied and connected to an upper part of the loose particles.

类似技术:

---

公开号 | 公开日 | 专利标题

---

BR112016008072B1|2021-06-22|METHOD FOR FORMING A WEAR RESISTANT DECORATIVE LAYER AND FLOOR PANEL

---

US10899121B2|2021-01-26|Digital print with water-based ink on panel surfaces

---

US11130352B2|2021-09-28|Digital binder and powder print

---

BR112015016163B1|2021-08-17|METHOD OF FORMATION OF A DIGITAL PRINT ON A PANEL

---

BR112015001612B1|2021-05-25|method of forming a digitally printed image with colored pigments on a building panel surface

---

BR112015016240A2|2021-05-25|digital recording

---

BR112015016197B1|2021-08-10|METHOD OF FORMATION OF A FINGERPRINT ON A SURFACE

---

ES2846001T3|2021-07-28|Dry ink for digital printing

同族专利:

---

公开号 | 公开日

---

KR102275050B1|2021-07-08|

---

EA201690781A1|2016-09-30|

---

CN105636787A|2016-06-01|

---

CA2926185A1|2015-04-30|

---

UA121105C2|2020-04-10|

---

EP3060400B1|2020-03-11|

---

EP3060400A4|2017-06-28|

---

EP3060400A1|2016-08-31|

---

PL3683055T3|2022-01-31|

---

CA2926185C|2021-11-09|

---

KR20160077099A|2016-07-01|

---

MX2016004966A|2016-06-28|

---

US20190263101A1|2019-08-29|

---

CN105636787B|2020-07-10|

---

US11077652B2|2021-08-03|

---

CN111923569A|2020-11-13|

---

EP3683055A1|2020-07-22|

---

EP3683055B1|2021-12-08|

---

US10328680B2|2019-06-25|

---

EA035277B1|2020-05-22|

---

US20160250835A1|2016-09-01|

---

WO2015060778A1|2015-04-30|

引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

---

US3210302A|1960-12-19|1965-10-05|Glidden Co|Emulsifiable composition of polyurethanes with metal-salt driers, anionic emulsifiers, and pigments|

---

US4554200A|1983-07-11|1985-11-19|American Hoechst Corporation|Polyester film primed with organic acid salts|

---

EP0445327B1|1990-03-07|1994-07-06|Felix Schoeller jr. Papierfabrik GmbH & Co. KG|Recording medium for ink-jet printing|

---

JP3125395B2|1991-12-12|2001-01-15|シーアイ化成株式会社|Cosmetic material using transfer sheet having antistatic function and method of manufacturing the same|

---

US5486231A|1994-05-02|1996-01-23|Dulaney; Donald C.|Water repellent solution for wood and method|

---

US8337006B2|1998-05-06|2012-12-25|Sawgrass Technologies, Inc.|Energy activated printing process|

---

US6084619A|1995-04-21|2000-07-04|Seiko Epson Corporation|Ink jet recording method|

---

DE19709735A1|1997-03-10|1998-09-17|Sihl Gmbh|Inkjet recording material|

---

US6270214B1|1998-04-29|2001-08-07|Xerox Corporation|Ink jet printing process with improved image fixation|

---

US6087416A|1998-07-22|2000-07-11|E.I. Du Pont De Nemours And Company|Aqueous pigmented ink jet inks for printing on vinyls|

---

US6310115B1|1998-10-29|2001-10-30|Agfa-Gevaert|Ink compositions for ink jet printing|

---

JP3678303B2|1999-04-01|2005-08-03|セイコーエプソン株式会社|Ink jet recording method for non-absorbent recording medium|

---

WO2001019618A1|1999-09-10|2001-03-22|Renolit-Werke Gmbh|Use of plastic films for printing with organic inks in an inkjet process|

---

SE516696C2|1999-12-23|2002-02-12|Perstorp Flooring Ab|Process for producing surface elements comprising an upper decorative layer as well as surface elements produced according to the method|

---

US6399670B1|2000-01-21|2002-06-04|Congoleum Corporation|Coating having macroscopic texture and process for making same|

---

JP3497437B2|2000-03-09|2004-02-16|東洋テックス株式会社|Manufacturing method of building decorative flooring|

---

PT1676720E|2000-06-13|2011-02-28|Flooring Ind Ltd|Floor covering|

---

GB0025886D0|2000-10-23|2000-12-06|Murray Nicholas J|Method and apparatus for producing a transfer image and method and apparatus for transfering a coating|

---

WO2002042087A2|2000-11-13|2002-05-30|Imaging Alternatives, Inc.|Wood surface inkjet receptor medium and method of making and using same|

---

US7081300B2|2001-01-22|2006-07-25|Formica Corporation|Decorative laminate assembly and method of producing same|

---

SE0101620D0|2001-05-10|2001-05-10|Pergo Ab|Embossed decorative boards|

---

DE10156956A1|2001-11-20|2003-06-05|Hw Ind Gmbh & Co Kg|Building components, especially floor tiles, are produced by forming a laminate from a carrier and a decorative paper, and applying a duroplastic|

---

EP1314766A1|2001-11-23|2003-05-28|Sicpa Holding S.A.|Pigmented ink composition|

---

SE525661C2|2002-03-20|2005-03-29|Vaelinge Innovation Ab|Floor boards decorative joint portion making system, has surface layer with underlying layer such that adjoining edge with surface has underlying layer parallel to horizontal plane|

---

US6585369B1|2002-04-17|2003-07-01|Hewlett-Packard Development Company, L.P.|Preparations for ink-jet printing on common household surfaces|

---

US6848777B2|2002-09-27|2005-02-01|Eastman Kodak Company|Aqueous inkjet ink and receiver combination|

---

US20040086678A1|2002-11-01|2004-05-06|Chen Hao A.|Surface covering panel|

---

DE10252865A1|2002-11-12|2004-05-27|Kronotec Ag|Process for creating a structured decoration in a wood-based panel|

---

DE10310199B4|2003-03-06|2007-09-20|Kronotec Ag|Wood fiber board and process for its production|

---

US7678425B2|2003-03-06|2010-03-16|Flooring Technologies Ltd.|Process for finishing a wooden board and wooden board produced by the process|

---

DE102004011531C5|2004-03-08|2014-03-06|Kronotec Ag|Wood-based panel, in particular floor panel|

---

US20050206705A1|2004-03-16|2005-09-22|Zeying Ma|Ink-jet imaging on offset media|

---

EP1584378A1|2004-04-08|2005-10-12|DSM IP Assets B.V.|Coated substrate|

---

US20050249929A1|2004-05-05|2005-11-10|Reichwein David P|Digitally printed surface covering|

---

US7383768B2|2004-05-05|2008-06-10|Awi Licensing Company|Rapid prototyping and filling commercial pipeline|

---

US7416594B2|2004-05-18|2008-08-26|Hewlett-Packard Development Company, L.P.|Pigments stabilized to acid challenge|

---

KR200370449Y1|2004-06-22|2004-12-17|주식회사 엘지화학|Flooring having surface layer of synthetic resin and wood-based board|

---

US20060194015A1|2004-11-05|2006-08-31|Vincente Sabater|Flooring system with slant pattern|

---

US8215078B2|2005-02-15|2012-07-10|Välinge Innovation Belgium BVBA|Building panel with compressed edges and method of making same|

---

EP1691005B1|2005-02-15|2009-08-19|Välinge Innovation AB|Method to make a floorboard with compressed edges|

---

US7841144B2|2005-03-30|2010-11-30|Valinge Innovation Ab|Mechanical locking system for panels and method of installing same|

---

JP4656505B2|2005-03-31|2011-03-23|セイコーエプソン株式会社|Treatment liquid for plastic film and ink jet recording method using the same|

---

US20080152825A1|2005-03-31|2008-06-26|Hiroshi Mukai|Treatment Liquid for Plastic Film, Primer Liquid for Printing, Ink Composition, and Method for Ink Jet Recording Using Them|

---

DE102005042658B3|2005-09-08|2007-03-01|Kronotec Ag|Tongued and grooved board for flooring has at least one side surface and tongue and/or groove with decorative layer applied|

---

JP2007106110A|2005-09-13|2007-04-26|Konica Minolta Holdings Inc|Image forming method|

---

BE1016846A3|2005-11-09|2007-08-07|Flooring Ind Ltd|Floor covering has hard floor panels having at least one chamfer having surface covered with separate decorative covering by transfer printing technique|

---

DE102006007976B4|2006-02-21|2007-11-08|Flooring Technologies Ltd.|Process for refining a building board|

---

US7918062B2|2006-06-08|2011-04-05|Mannington Mills, Inc.|Methods and systems for decorating bevel and other surfaces of laminated floorings|

---

SE533410C2|2006-07-11|2010-09-14|Vaelinge Innovation Ab|Floor panels with mechanical locking systems with a flexible and slidable tongue as well as heavy therefore|

---

DE502006005293D1|2006-08-25|2009-12-17|Homag Holzbearbeitungssysteme|Device for patterning workpieces|

---

SE531111C2|2006-12-08|2008-12-23|Vaelinge Innovation Ab|Mechanical locking of floor panels|

---

JP4277898B2|2006-12-25|2009-06-10|セイコーエプソン株式会社|Inkjet recording method|

---

JP5444591B2|2007-04-11|2014-03-19|コニカミノルタ株式会社|Water-based heat fixing type ink and heat fixing type ink jet recording method|

---

JP4867772B2|2007-04-24|2012-02-01|パナソニック電工株式会社|Cosmetic material|

---

US20100231671A1|2007-06-04|2010-09-16|E.I. Du Pont De Nemours And Company|Pretreatment for low and non-porous media for inkjet printing|

---

CN101532331A|2007-07-30|2009-09-16|诺瓦利斯股份有限公司|Floor covering with interlocking design|

---

JP2010536614A|2007-08-20|2010-12-02|ムーアウォリスノースアメリカ、インコーポレーテッド|Nanoparticle-based composition applicable to jet printing and printing method|

---

PL2242625T3|2007-11-19|2017-09-29|Välinge Innovation AB|Fibre based panels with a wear resistance surface|

---

EP3470193A1|2008-04-07|2019-04-17|Välinge Innovation AB|Wood fibre based panels with a thin surface layer|

---

DE102007062941B4|2007-12-21|2012-10-18|Surface Technologies Gmbh & Co. Kg|Process for producing a laminate|

---

EP2599934B1|2009-01-30|2018-10-10|Välinge Innovation AB|Mechanical locking of floor panels|

---

SG187516A1|2008-01-31|2013-02-28|Vaelinge Innovation Belgium Bvba|Please see remarks |

---

DE102008008292A1|2008-02-07|2009-08-13|hülsta-werke Hüls GmbH & Co KG|Paper layer for producing a flat, printed or printable component|

---

US20090219330A1|2008-02-28|2009-09-03|Kabushiki Kaisha Toshiba|Inkjet printing method, pretreatment liquid for inkjet printing and ink composition|

---

BE1018213A3|2008-07-14|2010-07-06|Flooring Ind Ltd Sarl|METHOD FOR MANUFACTURING COVERED PANELS AND COVERED PANEL OBTAINED HEREIN.|

---

EP2318465B1|2008-08-12|2016-10-26|Hewlett-Packard Development Company, L.P.|Inks with water soluble near ir dyes|

---

BE1018337A3|2008-11-13|2010-09-07|Flooring Ind Ltd Sarl|METHODS FOR MANUFACTURING PANELS AND PANEL OBTAINED HEREBY|

---

EP2385900B1|2008-12-17|2013-02-20|Basf Se|Printing press and method for printing a substrate|

---

KR101616593B1|2008-12-19|2016-05-12|플로어링 인더스트리즈 리미티드 에스에이알엘|Coated panel comprising foam or polyvinyl chloride and method for manufacturing|

---

EP2202056A1|2008-12-23|2010-06-30|Unilin Industries, BVBA|Floor panel and methods for manufacturing floor panels|

---

BE1018630A5|2009-01-20|2011-05-03|Flooring Ind Ltd Sarl|METHODS FOR MANUFACTURING PANELS AND PANEL OBTAINED HEREBY|

---

EP2213476A1|2009-01-30|2010-08-04|Spanolux N.V.- DIV. Balterio|A method of manufacturing a laminate panel, an apparatus and a laminate panel|

---

EP2264259B8|2009-06-17|2013-09-11|Välinge Innovation AB|Panel, use of a panel, method for manufacturing a panel and a prepreg|

---

EP2456833B1|2009-07-20|2017-04-12|Markem-Imaje Corporation|Solvent-based inkjet ink formulations|

---

ES2660198T3|2009-07-30|2018-03-21|Igm Group B.V.|Macrophotoinitiators|

---

DE102009043812B4|2009-08-19|2021-11-25|Hymmen GmbH Maschinen- und Anlagenbau|Process for producing a printed surface on a flat workpiece|

---

EP2473572A4|2009-09-03|2014-04-09|Hewlett Packard Development Co|Ink-jet ink printing system and method|

---

CN101738814B|2009-11-11|2013-09-18|广州奥翼电子科技有限公司|Electrophoresis disclosing solution and preparation method thereof|

---

US8574690B2|2009-12-17|2013-11-05|International Paper Company|Printable substrates with improved dry time and acceptable print density by using monovalent salts|

---

US8784587B2|2010-01-15|2014-07-22|Valinge Innovation Ab|Fibre based panels with a decorative wear resistance surface|

---

SG181545A1|2010-01-15|2012-07-30|Ceraloc Innovation Belgium|Bright colored surface layer|

---

AU2011207342A1|2010-01-22|2012-08-30|Octi-Tech Limited, Llc|Imaging process for flooring material|

---

AU2011220343A1|2010-02-25|2012-10-18|Depco-Trh Pty Ltd|Manufacture of a decorative laminate using UV cured printing inks|

---

CN102781677B|2010-02-26|2014-07-09|株式会社理光|Inkjet treatment liquid, inkjet recording apparatus, inkjet recording method and image formation|

---

JP2011201228A|2010-03-26|2011-10-13|Seiko Epson Corp|Ink jet recording process|

---

US10899166B2|2010-04-13|2021-01-26|Valinge Innovation Ab|Digitally injected designs in powder surfaces|

---

US8480841B2|2010-04-13|2013-07-09|Ceralog Innovation Belgium BVBA|Powder overlay|

---

WO2011129757A1|2010-04-13|2011-10-20|Ceraloc Innovation Belgium Bvba|Digitally injected designs in powder surfaces|

---

US8403461B2|2010-05-04|2013-03-26|Kabushiki Kaisha Toshiba|Aqueous inkjet ink|

---

WO2012004701A2|2010-07-09|2012-01-12|Flooring Industries Limited, Sarl|Floor panel|

---

BE1019331A5|2010-05-10|2012-06-05|Flooring Ind Ltd Sarl|FLOOR PANEL AND METHODS FOR MANUFACTURING FLOOR PANELS.|

---

BE1019501A5|2010-05-10|2012-08-07|Flooring Ind Ltd Sarl|FLOOR PANEL AND METHOD FOR MANUFACTURING FLOOR PANELS.|

---

US8721061B2|2010-05-21|2014-05-13|Hewlett-Packard Development Company, L.P.|Fluid ejection device with circulation pump|

---

WO2011146149A1|2010-05-21|2011-11-24|Hewlett-Packard Development Company, L.P.|Fluid ejection device with circulation pump|

---

EP2571696B1|2010-05-21|2019-08-07|Hewlett-Packard Development Company, L.P.|Fluid ejection device with circulation pump|

---

US9278515B2|2010-06-14|2016-03-08|Hewlett-Packard Development Company, L.P.|Printing method|

---

CN101885200B|2010-07-30|2011-12-28|浙江世友木业有限公司|Method for producing high-emulation three-dimensional wood floor and high-emulation 3D wood floor|

---

DE102010045266A1|2010-09-14|2012-03-15|Guido Schulte|Method for manufacturing component for lining of e.g. floor surface of building, involves applying upper decoration part of ink above non-woven fabric layer before or after applying non-woven fabric layer on base body|

---

JP2012077446A|2010-09-30|2012-04-19|Daiken Corp|Manufacturing method for floor constitution material|

---

US8491960B2|2010-11-01|2013-07-23|Vistaprint Technologies Limited|Method for producing raised print using dimensional ink and thermographic powder|

---

JP2012096511A|2010-11-05|2012-05-24|Fuji Xerox Co Ltd|Inkjet recording method, inkjet recording device and inkjet recording ink|

---

JP2012206488A|2011-03-30|2012-10-25|Seiko Epson Corp|Ink jet recording method|

---

CN103732407B|2011-08-26|2018-08-24|塞拉洛克创新股份有限公司|Plate application|

---

EP2623567B1|2012-02-03|2014-11-05|Agfa Graphics N.V.|Inkjet printing of wood colours|

---

DE102012008616A1|2012-04-27|2013-10-31|Hörmann KG Brockhagen|Method and device for producing a coated component|

---

US10369837B2|2012-04-30|2019-08-06|Valinge Innovation Ab|Method for forming a decorative design on an element of a wood-based material|

---

BE1020722A3|2012-06-01|2014-04-01|Unilin Bvba|PANEL FOR FORMING A FLOOR COVERING AND METHOD FOR MANUFACTURING SUCH PANELS.|

---

US20140017452A1|2012-07-13|2014-01-16|Floor Iptech Ab|Digital coating and printing|

---

EP2872260A4|2012-07-13|2016-08-17|Ceraloc Innovation Ab|Method of coating a building panel with digital printing/coating technique|

---

BR112015001612B1|2012-07-26|2021-05-25|Ceraloc Innovation Ab|method of forming a digitally printed image with colored pigments on a building panel surface|

---

US9446602B2|2012-07-26|2016-09-20|Ceraloc Innovation Ab|Digital binder printing|

---

GB201214552D0|2012-08-15|2012-09-26|Fujifilm Imaging Colorants Inc|Inks for ink-jet printing|

---

KR102193522B1|2012-11-28|2020-12-21|뵈린게 이노베이션 에이비이|Method of producing a building panel using digital printing|

---

US9409382B2|2012-11-28|2016-08-09|Valinge Innovation Ab|Method of producing a building panel|

---

US9528011B2|2013-01-11|2016-12-27|Ceraloc Innovation Ab|Digital binder and powder print|

---

EP3825137A1|2013-01-11|2021-05-26|Ceraloc Innovation AB|Digital binder and powder print|

---

JP5840660B2|2013-09-03|2016-01-06|富士フイルム株式会社|Inkjet ink composition and image recording method|

---

EP2865531B1|2013-10-22|2018-08-29|Agfa Nv|Inkjet printing methods for manufacturing of decorative surfaces|

---

EP2865527B1|2013-10-22|2018-02-21|Agfa Nv|Manufacturing of decorative surfaces by inkjet|

---

EP3683055B1|2013-10-23|2021-12-08|Ceraloc Innovation AB|Floor panel|

---

ES2752557T3|2014-01-10|2020-04-06|Unilin Bvba|Method for making panels with a decorative surface|

---

EP3096961B1|2014-01-24|2022-03-02|Ceraloc Innovation AB|Digital print with water-based ink on panel surfaces|

---

EP3099499A4|2014-01-31|2017-10-11|Ceraloc Innovation AB|A method of printing a digital image on a substrate attached to a panel and a water-based ink for digital printing on a substrate|

---

EP3433105A4|2016-03-24|2019-11-13|Välinge Innovation AB|A method for forming a décor on a substrate|CN103732407B|2011-08-26|2018-08-24|塞拉洛克创新股份有限公司|Plate application|

---

US10369837B2|2012-04-30|2019-08-06|Valinge Innovation Ab|Method for forming a decorative design on an element of a wood-based material|

---

EP3683055B1|2013-10-23|2021-12-08|Ceraloc Innovation AB|Floor panel|

---

EP3096961B1|2014-01-24|2022-03-02|Ceraloc Innovation AB|Digital print with water-based ink on panel surfaces|

---

EP3099499A4|2014-01-31|2017-10-11|Ceraloc Innovation AB|A method of printing a digital image on a substrate attached to a panel and a water-based ink for digital printing on a substrate|

---

NL2013046B1|2014-06-20|2016-07-06|Champion Link Int Corp|Panel suitable for assembling a waterproof floor or wall covering, method of producing a panel.|

---

DE102014009273A1|2014-06-26|2016-01-14|Hülsta-Werke Hüls Gmbh & Co. Kg|Decor system for a floor, wall or ceiling covering or for a furniture component|

---

EP3350387A1|2015-09-17|2018-07-25|Beaulieu International Group NV|Custom-made covering panels by digital printing of base panels|

---

EP3208086B1|2016-02-19|2018-10-10|Flooring Technologies Ltd.|Laminated wood-plastic composite materialdisc, and method for its preparation|

---

EP3433105A4|2016-03-24|2019-11-13|Välinge Innovation AB|A method for forming a décor on a substrate|

---

US11248380B2|2016-06-28|2022-02-15|Sunrise Spc Technology, Llc|Glueless dustless composite flooring material system|

---

US10889040B2|2016-06-28|2021-01-12|John B. Troendle|Method of producing a glueless dustless composite flooring material system|

---

US10220599B2|2016-06-28|2019-03-05|John B. Troendle|Glueless dustless composite flooring material system|

---

US10343381B2|2016-06-28|2019-07-09|John B. Troendle|Method of producing a glueless dustless composite flooring material system|

---

US10662656B2|2016-06-28|2020-05-26|John B. Troendle|Glueless dustless composite flooring material system|

---

WO2018097168A1|2016-11-28|2018-05-31|パナソニックＩｐマネジメント株式会社|Decorative surface panel, decorative panel equipped with same, and method for producing decorative surface panel|

---

EP3625409A4|2017-05-15|2021-02-24|Engineered Floors LLC|Floorcoverings with planarly variable properties|

---

CN107190579A|2017-06-22|2017-09-22|苏州市建诚装饰材料有限公司|A kind of colored wearing coat paper production technology|

---

CN107178002A|2017-06-22|2017-09-19|苏州市建诚装饰材料有限公司|A kind of wear-resisting colored overlay paper production technology|

---

CN109079933A|2018-07-24|2018-12-25|陈敏芬|The production technology of improved molding wooden piece coating melamine impregnation abrasion-proof paper|

---

KR20210060496A|2018-08-30|2021-05-26|인터페이스 인크.|Digital printing for flooring and decorative structures|

---

PL3632700T3|2018-10-02|2021-12-20|Akzenta Paneele + Profile Gmbh|Digitally printing structured wear protection film|

---

CN112996649A|2018-10-31|2021-06-18|J·F·巴伯兰拉托雷|Method for producing a three-dimensional structure on the surface of a flat substrate, resulting substrate and device for producing a substrate according to said method|

---

EP3666483A1|2018-12-13|2020-06-17|Lamett Europe|Flooring engineered plank having 3d effect and its manufacturing method|

---

US11097512B1|2020-01-31|2021-08-24|Champion Link Intern Aiton Al Corporation|Floor panel and method of manufacturing a floor panel|

---

US11053696B1|2020-01-31|2021-07-06|Champion Link International Corporation|Panel for forming a floor covering and such floor covering|

---

US11149441B2|2020-03-13|2021-10-19|Champion Link International Corporation|Panel and method of producing a panel|

法律状态:
2018-04-03| B25A| Requested transfer of rights approved|Owner name: CERALOC INNOVATION AB (SE) |

---

2020-01-28| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

---

2021-05-11| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

---

2021-06-22| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/10/2014, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

---

申请号 | 申请日 | 专利标题

---

SE1351260-3|2013-10-23|

---

SE1351260|2013-10-23|

---

PCT/SE2014/051246|WO2015060778A1|2013-10-23|2014-10-22|Method of forming a decorative wear resistant layer|

---